ChemInform Abstract: Synthesis of 1,2-Bisalkylidenecyclopentanes from 1,6-Allenynes via Stereoselective Addition of Nucleophiles to Ruthenacyclopentenes.
β Scribed by Nozomi Saito; Yuh Kohyama; Yuki Tanaka; Yoshihiro Sato
- Book ID
- 112048833
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 47 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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Hypervalent Iodine Induced Nucleophilic Additions to Alkenes: Synthesis of 1,2-Diperchlorates. -Bis(perchlorate)iodo benzene, generated in situ from a reagent combination Mg(ClO 4 ) 2 /Ph-J(O-Ac) 2 and stable in a pure form at 25 β’ C for weeks, is found to be effective for the conversion of unactiva