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ChemInform Abstract: Regioselective Addition of Allylindium Reagents to Allenes in Functionalized 1,6-Diols Bearing Allenynes.

✍ Scribed by Sundae Kim; Phil Ho Lee


Publisher
John Wiley and Sons
Year
2008
Weight
28 KB
Volume
39
Category
Article
ISSN
0931-7597

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Regioselective Addition of Allylindium R
✍ Sundae Kim; Phil Ho Lee πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 144 KB

## Abstract Addition reactions of allylindium reagents generated in situ from indium and allyl halides to functionalized allenyne 1,6‐diols proceeded regioselectively through anti‐Markovnikov addition to produce exclusively dienyne 1,6‐diols in good yields in THF at 70 Β°C. In the case of 3‐bromo‐2‐