ChemInform Abstract: Hypervalent Iodine Induced Nucleophilic Additions to Alkenes: Synthesis of 1,2-Diperchlorates.

✍ Scribed by A. DE MICO; R. MARGARITA; L. PARLANTI; G. PIANCATELLI; A. VESCOVI

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 33 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199811091

✦ Synopsis

Hypervalent Iodine Induced Nucleophilic Additions to Alkenes: Synthesis of 1,2-Diperchlorates. -Bis(perchlorate)iodo benzene, generated in situ from a reagent combination Mg(ClO 4 ) 2 /Ph-J(O-Ac) 2 and stable in a pure form at 25 • C for weeks, is found to be effective for the conversion of unactivated alkenes to the corresponding 1,2-diperchlorates. -(DE MICO, A.