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ChemInform Abstract: Synthesis of (1.1.1)Propellanes by Bridging of Bicyclo(1.1.0)butanes.

✍ Scribed by M. WERNER; D. S. STEPHENSON; G. SZEIMIES


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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2. Addition of Lip-thiocresolate gives a mixture of ( l ) , (Ia), ( l b ) , ( l c ) , i.e. p-tolylthio groups are incorporated into the carbenoid via (2) ; after a reaction time of 20 h at a temperature of -lOΒ°C the mixture was hydrolysed with D2O and H20 and the formation of the lithium compounds (