Synthesis and Properties of 1-Azabicyclo[1.1.0]butanes
โ Scribed by Dr. W. Funke
- Publisher
- John Wiley and Sons
- Year
- 1969
- Tongue
- English
- Weight
- 235 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
2. Addition of Lip-thiocresolate gives a mixture of ( l ) , (Ia), ( l b ) , ( l c ) , i.e. p-tolylthio groups are incorporated into the carbenoid via (2) ; after a reaction time of 20 h at a temperature of -lOยฐC the mixture was hydrolysed with D2O and H20 and the formation of the lithium compounds (
Solvolysis products of 3-azetidinyl chlorides, tosylates, and mesylates have been interpreted previously to indicate that these reactions proceed by azabicyclo[1.1.0]butyl cationic intermediates. Whether these cations are formed by direct ionization to 3-azetidinyl cations followed by collapse to th
responding silyl derivatives of 7 , 8, and 9, which, because of their expected better solubility, will facilitate further physical and chemical investigations of this class of compounds.