Pb 6 Re 6 O 19 oxide has been synthesized in a sealed evacuted silica tube and by high-pressure high-temperature technique. Its crystal structure, refined from X-ray powder data (a = 9.3162(1) A Γ , space group Pn3, R I = 0.021, R p = 0.067), is based on a three-dimensional network of Re 2 O 10 grou
ChemInform Abstract: Synthesis and Structure of the Double Oxide Pb6Re6O19.
β Scribed by A. M. ABAKUMOV; R. V. SHPANCHENKO; E. V. ANTIPOV
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Synthesis and Crystal Structure of Rb 6 Pb 5 Cl 16 . -The hitherto unknown 6:5 phase of title is prepared by reaction of appropriate amounts of RbCl and PbCl 2 (sealed silica tube, 1. 500 β’ C, 0.5 h, 2. 335 β’ C, several weeks). Rb 6 Pb 5 Cl 16 crystallizes in the tetragonal space group P4/mbm (pow