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ChemInform Abstract: Synthesis and Crystal Structure of Rb6Pb5Cl16.

โœ Scribed by H. P. BECK; M. SCHRAMM; R. HABERKORN; R. DINNEBIER; P. W. STEPHENS

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Synthesis and Crystal Structure of Rb 6 Pb 5 Cl 16 .

-The hitherto unknown 6:5 phase of title is prepared by reaction of appropriate amounts of RbCl and PbCl 2 (sealed silica tube, 1. 500 โ€ข C, 0.5 h, 2. 335 โ€ข C, several weeks).

Rb 6 Pb 5 Cl 16 crystallizes in the tetragonal space group P4/mbm (powder synchrotron XRD). A special feature of the structure is the statistical distribution of Rb and Pb at one of the cation sites with a ratio of 1:3 as defined by electroneutrality. -(BECK, H.

๐Ÿ“œ SIMILAR VOLUMES

Synthesis and Crystal Structure of Rb6Pb
Synthesis and Crystal Structure of Rb6Pb5Cl16
โœ Horst P. Beck; Manfred Schramm; Robert Haberkorn; Robert Dinnebier; Peter W. Ste ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 173 KB ๐Ÿ‘ 2 views

The synthesis of a hitherto unknown 6 : 5 phase in the quasi-binary system RbCl/PbCl 2 and its structure determination is reported. The compound Rb 6 Pb 5 Cl 16 crystallizes in the tetragonal space group P4/mbm with a large variety of different coordination polyhedra for the cations. Special feature