Synthesis and Crystal Structure of Rb 6 Pb 5 Cl 16 . -The hitherto unknown 6:5 phase of title is prepared by reaction of appropriate amounts of RbCl and PbCl 2 (sealed silica tube, 1. 500 โข C, 0.5 h, 2. 335 โข C, several weeks). Rb 6 Pb 5 Cl 16 crystallizes in the tetragonal space group P4/mbm (pow
โฆ LIBER โฆ
ChemInform Abstract: Synthesis and Crystal Structure of Rb3PbCl5.
โ Scribed by H. P. Beck; H. Monzel; R. Haberkorn; P. W. Stephens; R. Dinnebier
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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The synthesis of a hitherto unknown 6 : 5 phase in the quasi-binary system RbCl/PbCl 2 and its structure determination is reported. The compound Rb 6 Pb 5 Cl 16 crystallizes in the tetragonal space group P4/mbm with a large variety of different coordination polyhedra for the cations. Special feature