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ChemInform Abstract: Synthesis and Reactions of Chiral α-Lithiophosphoric Triamides.

✍ Scribed by J. F. K. MUELLER; B. SPINGLER; M. ZEHNDER

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis and Reactions of Chiral α-Lithiophosphoric Triamides. -The reaction of the chiral phosphoric diamide (I) with N-methylbenzylamine yields the triamide (III). Regioselective lithiation and addition of electrophiles gives alkylated or stannylated products with moderate diastereoselectivity. -(MUELLER,

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