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ChemInform Abstract: Intramolecular Carbolithiation Reactions of Chiral α-Amino-organolithium Species.

✍ Scribed by Neil J. Ashweek; Iain Coldham; David J. Snowden; Graham P. Vennall

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
33
Category
Article
ISSN
0931-7597

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Intramolecular Carbolithiation Reactions
Intramolecular Carbolithiation Reactions of Chiral α-Amino-organolithium Species
✍ Neil J. Ashweek; Iain Coldham; David J. Snowden; Graham P. Vennall 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 334 KB

Enantiomerically enriched alpha-amino-organolithium species, in which the lithium atom is attached to a stereogenic carbon centre, have been found to be chemically stable at room temperature in a solvent of very low polarity and undergo intramolecular carbolithiation onto an unactivated alkene. The