The chiral α-bromo α,β-unsaturated esters 3 and 9 are react with the kinetic lithium dienolates of enone 10 to give functionalized tricyclo[3.2.1.0 2,7 ]octanes 11. Esters 3 give one prepared by asymmetric Sharpless dihydroxylation (AD) of 5 and from ester 7 and the chiral diols 8 by transacetalizat
✦ LIBER ✦
ChemInform Abstract: Synthesis and Anionically Induced Domino Reactions of Chiral α-Bromo α,β-Unsaturated Esters.
✍ Scribed by N. A. BRAUN; U. BUERKLE; M. P. FETH; I. KLEIN; D. SPITZNER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 38 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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