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ChemInform Abstract: Synthesis and Incorporation into α-DNA of a Novel Conformationally Constrained α-Nucleoside Analogue.

✍ Scribed by Bernhard M. Keller; Christian J. Leumann

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
33
Category
Article
ISSN
0931-7597

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Novel Enantioselective Synthesis of trans-α-(2-Carboxycycloprop-1yl)glycines: Conformationally Constrained L-Glutamate Analogues. -Key step of the described sequence is the oxazaborolidine-catalyzed enantioselective conversion of oxime ethers (V) and (VI) to the corresponding amines. Interestingly,