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ChemInform Abstract: Novel Enantioselective Synthesis of trans-α-(2-Carboxycycloprop-1-yl)glycines: Conformationally Constrained L-Glutamate Analogues.

✍ Scribed by A. S. DEMIR; C. TANYELI; A. CAGIR; M. N. TAHIR; D. ULKU

Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Novel Enantioselective Synthesis of trans-α-(2-Carboxycycloprop-1yl)glycines: Conformationally Constrained L-Glutamate Analogues.

-Key step of the described sequence is the oxazaborolidine-catalyzed enantioselective conversion of oxime ethers (V) and (VI) to the corresponding amines. Interestingly, the stereochemical outcome of this reaction is governed by the oxime geometry.

-(DEMIR, A.

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