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ChemInform Abstract: Syntheses with Organoboranes. Part 11. Allylboration of Vinylic Epoxides with Allylic Dialkylboranes.

✍ Scribed by Marek Zaidlewicz; Marek P. Krzeminski

Publisher: John Wiley and Sons
Year: 2001
Weight: 29 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200115039

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ChemInform Abstract: Simple Synthetic Method of Allyl- and Vinyl-Epoxides by Allylation of Carbonyl Groups with Allylic Tins Catalyzed by PbI2—HMPA.

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Simple Synthetic Method of Allyl-and Vinyl-Epoxides by Allylation of Carbonyl Groups with Allylic Tins Catalyzed by PbI 2 -HMPA. -The PbI 2 -HMPA catalyzed chemoselective carbonyl-allylation in α-halo ketones to achieve one-pot preparation of allyl epoxides (III) is presented. Moreover a simple and

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Syntheses with Organoboranes. Part 7. Monohydroboration of Conjugated Dienes with Catecholborane Catalyzed by Complexes of Nickel(II) Chloride and Cobalt(II) Chloride with Diphosphines. -The hydroboration of dienes such as (I) and (V) with catecholborane in the presence of catalytic amounts of dich