ChemInform Abstract: Studies Towards the Total Synthesis of Altohyrtin A: A Convergent Approach to the C38—C51 Carbon Framework.
✍ Scribed by Pierre D. Kary; Stanley M. Roberts; Daniel J. Watson
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Toward a Total Synthesis of Pristinamycin II B ; a Chiron Approach to a C-9/C-16 Fragment. -Starting from readily available (S)-malic acid derivative (I), an appreciable amount (ca. 2 g) of the title fragment (XV) is prepared using the Grignard reaction of the propargyl diol (VI) as the key step. T
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