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ChemInform Abstract: A New Convergent Approach to the Polycyclic Framework of Dynemicin A.

✍ Scribed by S. ESCUDERO; D. PEREZ; E. GUITIAN; L. CASTEDO

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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The convergent approach to a broad variety of functionalized alkynes starts with a Knoevenagel-type condensation of 4-unsubstituted isoxazolines with ketones or aldehydes. The resulting adducts are subjected to Michael addition with various nucleophiles such as hydride, cyanide or phosphite. Exposur