ChemInform Abstract: Stereoselectivity of Methyl Aryldiazoacetate Cyclopropanations of 1,1-Diarylethylene. Asymmetric Synthesis of a Cyclopropyl Analogue of Tamoxifen.
β Scribed by Huw M. Davies; Tadamichi Nagashima; James L. Klino III
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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Stereoselective Synthesis of Cyclopropane-1,2-bis(glycine) Derivatives. -The synthesis of the title compounds (VII) and (VIII) is achieved via stereoselective azidation of the trans-cyclopropane derivative (III). Interestingly, under similar conditions the cis-isomer (IX) reacts differently yieldin
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