ChemInform Abstract: Stereoselective Synthesis of Cyclopropane-1,2-bis(glycine) Derivatives.

✍ Scribed by S. NESET; H. HOPE; K. UNDHEIM

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 31 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199751205

✦ Synopsis

Stereoselective Synthesis of Cyclopropane-1,2-bis(glycine) Derivatives.

-The synthesis of the title compounds (VII) and (VIII) is achieved via stereoselective azidation of the trans-cyclopropane derivative (III). Interestingly, under similar conditions the cis-isomer (IX) reacts differently yielding the bicyclic compound (XI). -(NESET, S.;