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ChemInform Abstract: Stereoselective Synthesis of Cyclopropanes Bearing Adjacent Stereocenters.

✍ Scribed by Janine Cossy; Nicolas Blanchard; Christophe Meyer

Publisher: John Wiley and Sons
Year: 2010
Weight: 40 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199937075

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Stereoselective Synthesis of Cyclopropane-1,2-bis(glycine) Derivatives. -The synthesis of the title compounds (VII) and (VIII) is achieved via stereoselective azidation of the trans-cyclopropane derivative (III). Interestingly, under similar conditions the cis-isomer (IX) reacts differently yieldin