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ChemInform Abstract: A Stereoselective Synthesis of 1β-Aminocarbapenems.

✍ Scribed by Kyung Jae Seo; Tae Ho Lee; Youn Young Lee

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereoselective Syn
ChemInform Abstract: Stereoselective Synthesis of β-Hydroxycyclohexanones.
✍ A. P. RUTHERFORD; C. S. GIBB; R. C. HARTLEY 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

Stereoselective Synthesis of β-Hydroxycyclohexanones. -A stereoselective route to β-hydroxycyclohexanones is reported. Thus Takai alkylidenation of the aldol (I) followed by desilylation and a novel anionic oxy-Cope rearrangement provides an enolate which undergoes 6-(enolendo)-exo-trig cyclization