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ChemInform Abstract: Direct Stereoselective Synthesis of β-Thiomannosides.

✍ Scribed by David Crich; Hongmei Li

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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✍ A. P. RUTHERFORD; C. S. GIBB; R. C. HARTLEY 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Stereoselective Synthesis of β-Hydroxycyclohexanones. -A stereoselective route to β-hydroxycyclohexanones is reported. Thus Takai alkylidenation of the aldol (I) followed by desilylation and a novel anionic oxy-Cope rearrangement provides an enolate which undergoes 6-(enolendo)-exo-trig cyclization