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ChemInform Abstract: Stereoselectivity in Aldol Reactions of Chiral N-Acyl Selones.

✍ Scribed by Zizhong Li; Ruilian Wu; Ryszard Michalczyk; R. Bruce Dunlap; Jerome D. Odom; Louis A. Silks III

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200015032

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## Stereoselective Grignard-Type Reactions of Chiral N,N-Dibenzylamino Ketones. -Enantiomerically pure N,N-dibenzylamino ketones (I), derived from chiral α-amino acids, react under nonchelating conditions with organometal reagents of type RLi, RMgX, RCeCl 2 . The reactions proceed highly diastere