β Scribed by D. CAVALLA; C. GUEGUEN; A. NELSON; P. O'BRIEN; M. G. RUSSELL; S. WARREN
No coin nor oath required. For personal study only.
1997 organo-phosphorus compounds, isocyclic C derivatives organo-phosphorus compounds, isocyclic C derivatives S 0084 03 -221 Chiral Phosphine Oxides and Chiral Esters in Stereoselective Intermolecular Acylation Reactions of Phosphine Oxides.
-Acylation of the phosphine oxide (I) generates diastereomeric products with a ratio depending on the work-up conditions. Stereoselective reduction of the purified diastereomers gives the corresponding alcohols highly selectively. A similar sequence is applied to the ester (VII) or the enantiomerically enriched phosphine oxide (XI).
π SIMILAR VOLUMES
## Abstract Under optimized conditions, a range of ketones reacts with 2 equiv.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v