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ChemInform Abstract: Stereoselective Synthesis of Vinyl-Substituted (Z)-Stilbenes by Rhodium-Catalyzed Addition of Arylboronic Acids to Allenic Alcohols.

✍ Scribed by Tomoya Miura; Hiroshi Shimizu; Tomohiro Igarashi; Masahiro Murakami

Publisher: John Wiley and Sons
Year: 2011
Weight: 44 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201106030

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✦ Synopsis

Abstract

The stereochemical outcome of the reaction is opposite to that of the corresponding reaction of (I) and (II) using a palladium catalyst which selectively produces (E)‐isomers.

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