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ChemInform Abstract: New Synthesis of Furans: The Rhodium-Catalyzed Carbonylative Addition of Arylboronic Acids to Propargylic Alcohols/Cyclization Sequence.

✍ Scribed by Julien Dheur; Mathieu Sauthier; Yves Castanet; Andre Mortreux

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
41
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

New Synthesis of Furans: the Rhodium-Cat
New Synthesis of Furans: the Rhodium-Catalysed Carbonylative Addition of Arylboronic Acids to Propargylic Alcohols/ Cyclisation Sequence
✍ Julien Dheur; Mathieu Sauthier; Yves Castanet; AndrΓ© Mortreux πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 208 KB

## Abstract The rhodium‐catalysed carbonylative addition of arylboronic acids to propargylic alcohols yields gamma‐hydroxy enones that are readily cyclised through a dehydration step to the corresponding furan analogues. The transformation was improved thanks to the screening of the reaction condit

ChemInform Abstract: Stereoselective Syn
ChemInform Abstract: Stereoselective Synthesis of Vinyl-Substituted (Z)-Stilbenes by Rhodium-Catalyzed Addition of Arylboronic Acids to Allenic Alcohols.
✍ Tomoya Miura; Hiroshi Shimizu; Tomohiro Igarashi; Masahiro Murakami πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 44 KB

## Abstract The stereochemical outcome of the reaction is opposite to that of the corresponding reaction of (I) and (II) using a palladium catalyst which selectively produces (E)‐isomers.