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ChemInform Abstract: Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to 2-Nitrostyrenes by tert-Butanesulfinylphosphine Ligand.

✍ Scribed by Feng Lang; Guihua Chen; Liangchun Li; Junwei Xing; Fuzhong Han; Linfeng Cun; Jian Liao

Publisher: John Wiley and Sons
Year: 2011
Weight: 37 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201134062

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Rhodium-Catalyzed Highly Enantioselectiv

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ChemInform Abstract: tert-Butanesulfinyl

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tert-Butanesulfinylphosphines: Simple Ch

tert-Butanesulfinylphosphines: Simple Chiral Ligands in Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Electron-Deficient Olefins

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## Abstract An efficient rhodium complex catalyst system was developed by using a class of simple __tert__‐butanesulfinylphosphines as bidentate ligands, which solely bear sulfur chirality and combine the advantages of both sulfoxide and phosphine ligands. Excellent activities (in 0.5 hour, up to 9

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ChemInform Abstract: Enantioselective Rh

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v