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Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to 2-Nitrostyrenes by tert-Butanesulfinylphosphine Ligand

✍ Scribed by Feng Lang; Guihua Chen; Dr. Liangchun Li; Junwei Xing; Fuzhong Han; Linfeng Cun; Prof. Dr. Jian Liao

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 320 KB
Volume: 17
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201100135

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## Abstract An efficient rhodium complex catalyst system was developed by using a class of simple __tert__‐butanesulfinylphosphines as bidentate ligands, which solely bear sulfur chirality and combine the advantages of both sulfoxide and phosphine ligands. Excellent activities (in 0.5 hour, up to 9

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