ChemInform Abstract: Stereoselective Synthesis of 8,9-Licarinediols.
β Scribed by Isabele R. Nascimento; Lucia M. X. Lopes; Laurence B. Davin; Norman G. Lewis
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 30 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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## Abstract A stereoselective synthesis of the title compound [8βazaβ9,11βethenoβPGH~1~ (3)] starting from butyl 2β(__p__βtolylsulfonyl)β2βazabicyclo[2.2.1]heptβ5βeneβ__exo__β3βcarboxylate (**5**) is described.
Stereoselective Syntheses of (+)-Goniotriol, (+)-8-Acetylgoniotriol, (+)-Goniodiol, (+)-9-Deoxygoniopypyrone, (+)-Altholactone, and (-)-Goniofupyrone. -Asymmetric syntheses of the title compounds (VIb), (VIc), (VIa), (X), (XIII), (XVI), belonging to the cytotoxic styryllactones, are achieved starti