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ChemInform Abstract: Stereoselective Syntheses of (+)-Goniotriol, (+)-8-Acetylgoniotriol, (+)-Goniodiol, (+)-9-Deoxygoniopypyrone, (+)-Altholactone, and (-)-Goniofupyrone.

✍ Scribed by C. MUKAI; S. HIRAI; M. HANAOKA

Publisher: John Wiley and Sons
Year: 2010
Weight: 43 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199804237

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✦ Synopsis

Stereoselective Syntheses of (+)-Goniotriol, (+)-8-Acetylgoniotriol, (+)-Goniodiol, (+)-9-Deoxygoniopypyrone, (+)-Altholactone, and (-)-Goniofupyrone.

-Asymmetric syntheses of the title compounds (VIb), (VIc), (VIa), (X), (XIII), (XVI), belonging to the cytotoxic styryllactones, are achieved starting from key intermediate (III) which is obtained from (I) that refers to known compound (II).

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ChemInform Abstract: Stereocontrolled Sy

ChemInform Abstract: Stereocontrolled Syntheses of Novel Styryl Lactones, (+)-Goniodiol, (+)-Goniotriol, (+)-8-Acetylgoniotriol, (+)-Goniofufurone, (+)-9-Deoxygoniopypyrone, (+)-Goniopypyrone, and (+)-Altholactone from Common Intermediates and Cytotoxicity of Their Congeners.

✍ Masayoshi Tsubuki; Kazuo Kanai; Hiromasa Nagase; Toshio Honda 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Stereocontrolled Syntheses of Novel Styryl Lactones, (+)-Goniodiol, (+)-Goniotriol, (+)-8-Acetylgoniotriol, (+)-Goniofufurone, (+)-9-Deoxygoniopypyrone, (+)-Goniopypyrone, and (+)-Altholactone from Common Intermediates and Cytotoxicity of Their Congeners. -The title lactones except goniofufurone (V