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ChemInform Abstract: Stereoselective Radical Bromination of α-Chloro Hydrocinnamic Acid Derivatives.

✍ Scribed by Leh See Wong; Bun Chan; Eng Wui Tan

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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Tetrahydrofuran α-Azido Esters: Precursors of Anomeric α-Amino Acid Monomers via Radical Bromination. -Highly selective radical bromination of protected carbohydrate C-glycosyl derivatives such as (I) and (IV) gives α-bromo esters which undergo displacement by azide to afford α