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ChemInform Abstract: Tetrahydrofuran α-Azido Esters: Precursors of Anomeric α-Amino Acid Monomers via Radical Bromination.

✍ Scribed by Martin D. Smith; Daniel D. Long; Angeles Martin; Neil Campbell; Yves Bleriot; George W. J. Fleet

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199942228

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✦ Synopsis

Tetrahydrofuran α-Azido Esters: Precursors of Anomeric α-Amino Acid Monomers via Radical Bromination.

-Highly selective radical bromination of protected carbohydrate C-glycosyl derivatives such as (I) and (IV) gives α-bromo esters which undergo displacement by azide to afford α

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