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ChemInform Abstract: Stereocontrolled Total Synthesis of (.+-.)-Culmorin via the Intramolecular Double Michael Addition.

โœ Scribed by Kiyosei Takasu; Sayaka Mizutani; Miho Noguchi; Kei Makita; Masataka Ihara

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Stereocontrolled Total Synthesis of (ยฑ)-Culmorin via the Intramolecular Double Michael Addition.

-The stereocontrolled total synthesis of racemic culmorin (VII) is based on the intramolecular double Michael addition of the cyclopentenone (V) having an ฮฑ,ฮฒ-unsaturated ester moiety. -

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ChemInform Abstract: Stereocontrolled Synthesis of ฮฒ-2โ€ฒ-Deoxypyrimidine Nucleosides via Intramolecular Glycosylations.
โœ X. XIA; J. WANG; M. W. HAGER; N. SISTI; D. C. LIOTTA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB ๐Ÿ‘ 1 views

Stereocontrolled Synthesis of ฮฒ-2'-Deoxypyrimidine Nucleosides via Intramolecular Glycosylations. -In continuation of efforts to develop general methods for the exclusive formation of ฮฒ-nucleosides, the base-promoted reaction of the pentafuranoside (II) with allyloxypyrimidines (II) is reported. Af