Substrates (VII) and (VIII) are prepared starting from the tricyclic ketone (I). Best yields concerning the desired title ring systems (IX) and (X) are obtained under the optimized cyclization conditions shown in the scheme. -(IHARA,
ChemInform Abstract: Stereoselective Synthesis of (.+-.)-Cedranediol via Intramolecular Double Michael Reaction.
β Scribed by K. MAKITA; K. FUKUMOTO; M. IHARA
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Stereocontrolled Total Synthesis of (Β±)-Culmorin via the Intramolecular Double Michael Addition. -The stereocontrolled total synthesis of racemic culmorin (VII) is based on the intramolecular double Michael addition of the cyclopentenone (V) having an Ξ±,Ξ²-unsaturated ester moiety. -
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