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ChemInform Abstract: Intramolecular Michael Addition Reaction for the Synthesis of Benzylbutyrolactones.

✍ Scribed by Hu He; Li-Xin Dai; Shu-Li You

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
41
Category
Article
ISSN
0931-7597

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Stereocontrolled Total Synthesis of (Β±)-Culmorin via the Intramolecular Double Michael Addition. -The stereocontrolled total synthesis of racemic culmorin (VII) is based on the intramolecular double Michael addition of the cyclopentenone (V) having an Ξ±,Ξ²-unsaturated ester moiety. -