ChemInform Abstract: Stereocontrolled Synthesis of 5α- and 5β-Substituted Kainic Acids.
✍ Scribed by Ivan Collado; Jesus Ezquerra; Ana I. Mateo; Concepcion Pedregal; Almudena Rubio
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
A Formal Synthesis of (-)-α-Kainic Acid. -Starting from Lpyroglutamic acid (-)-(I), the known precursor (-)-(XVI) for the synthesis of the title compound is presented. The key step in this approach is the SmI 2 -mediated ketyl radical cyclization of the enecarbamate (X). Under irradiation condition
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