ChemInform Abstract: Solvent-Mediated Allylation of Carbonyl Compounds with Allylic Stannanes.
β Scribed by T. M. COKLEY; P. J. HARVEY; R. L. MARSHALL; A. MCCLUSKEY; D. J. YOUNG
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
Metal-Mediated Barbier-Type Carbonyl Allylation under Solvent-Free Conditions. -In the title reaction no competing coupling products are observed which could be expected from a free-radical mechanism. A [4 + 2] cycloaddition mechanism is therefore proposed. If zinc or tin is used instead of indium,