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Gallium Metal Mediated Allylation of Carbonyl Compounds and Imines under Solvent-Free Conditions.

โœ Scribed by Philip C. Andrews; Anna C. Peatt; Colin L. Raston


Publisher
John Wiley and Sons
Year
2004
Weight
126 KB
Volume
35
Category
Article
ISSN
0931-7597

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Metal-Mediated Barbier-Type Carbonyl Allylation under Solvent-Free Conditions. -In the title reaction no competing coupling products are observed which could be expected from a free-radical mechanism. A [4 + 2] cycloaddition mechanism is therefore proposed. If zinc or tin is used instead of indium,

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