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ChemInform Abstract: Short Formal Synthesis of (-)-Platencin (VIII).

✍ Scribed by Konrad Tiefenbacher; Johann Mulzer

Publisher
John Wiley and Sons
Year
2008
Weight
40 KB
Volume
39
Category
Article
ISSN
0931-7597

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## Abstract **The right bicycle**: A concise formal synthesis of platencin was based on an efficient oxygen‐mediated palladium‐catalyzed cycloalkenylation of **1** to form a bicyclo[3.2.1]octane, and a deoxygenative rearrangement of tosylhydrazone **2** to construct the bicyclo[2.2.2]octane **3**.

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## Abstract **Der richtige Bicyclus**: Die effiziente sauerstoffvermittelte palladiumkatalysierte Cycloalkenylierung von **1** zu einem Bicyclo[3.2.1]octan und die desoxygenierende Umlagerung des Tosylhydrazons **2** zum Bicyclo[2.2.2]octan **3** sind wesentliche Schritte der Synthese der Kernstruk