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ChemInform Abstract: Scandium Triflate Catalyzed Diazocarbonyl Insertions into Heteroatom—Hydrogen Bonds.

✍ Scribed by Sunil V. Pansare; Rajendra P. Jain; Annyt Bhattacharyya

Book ID
101890235
Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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Scandium triflate catalyzed diazocarbony
Scandium triflate catalyzed diazocarbonyl insertions into heteroatomhydrogen bonds
✍ Sunil V. Pansare; Rajendra P. Jain; Annyt Bhattacharyya 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 260 KB

Scandium triflate is an efficient catalyst for diazocarbonyl insertion reactions into O-H, S-H and carbamate N-H bonds. The O-H and S-H insertion reactions proceed at ambient temperature and selective O-H insertion is possible in the presence of a earbamate N-H. A novel approach to a-amino acids inv