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ChemInform Abstract: Copper-Catalyzed Enantioselective Carbenoid Insertion into S—H Bonds.

✍ Scribed by Yong-Zhen Zhang; Shou-Fei Zhu; Yan Cai; Hong-Xiang Mao; Qi-Lin Zhou

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
41
Category
Article
ISSN
0931-7597

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Copper-Catalyzed Highly Enantioselective
Copper-Catalyzed Highly Enantioselective Carbenoid Insertion into SiH Bonds
✍ Yong-Zhen Zhang; Shou-Fei Zhu; Li-Xin Wang; Qi-Lin Zhou 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 272 KB

Chiral silanes are versatile intermediates for stereoselective transformations in organic synthesis. [1] Transition-metal-catalyzed carbenoid insertion into SiÀH bonds provides a direct and efficient method for the synthesis of silane-containing compounds. [2] The most popular catalysts used in SiÀH