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Copper-Catalyzed Highly Enantioselective Carbenoid Insertion into SiH Bonds

โœ Scribed by Yong-Zhen Zhang; Shou-Fei Zhu; Li-Xin Wang; Qi-Lin Zhou


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
272 KB
Volume
47
Category
Article
ISSN
0044-8249

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Copper-Catalyzed Highly Enantioselective
โœ Yong-Zhen Zhang; Shou-Fei Zhu; Li-Xin Wang; Qi-Lin Zhou ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 272 KB

Chiral silanes are versatile intermediates for stereoselective transformations in organic synthesis. [1] Transition-metal-catalyzed carbenoid insertion into Siร€H bonds provides a direct and efficient method for the synthesis of silane-containing compounds. [2] The most popular catalysts used in Siร€H