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ChemInform Abstract: Samarium Diiodide Promoted Coupling of Thiophenecarbaldehydes.

✍ Scribed by S.-M. YANG; J.-M. FANG


Book ID
112028243
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Novel Cyclodimeri
✍ L. ZHOU; Y. ZHANG πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 34 KB πŸ‘ 2 views

A Novel Cyclodimerization of Arylidenecyanoacetate Promoted by Samarium Diiodide. -Reductive treatment of arylidenecyanoacetates with SmI 2 results in cyclodimerization to the aminocyclopentenes (II). However, the hydroxyphenyl-substituted substrate yields only the double bond reductive product (VI