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Coupling Reactions and Coupling−Alkylations of Thiophenecarbaldehydes Promoted by Samarium Diiodide

✍ Scribed by Yang, Shyh-Ming; Fang, Jim-Min

Book ID
126105957
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
96 KB
Volume
64
Category
Article
ISSN
0022-3263

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✍ Gary A. Molander; Caryn Kenny 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 235 KB

The stereocontrolled intramolecular coupling of unsaturated P-ketoesters and pketoamides is reported. Good yields of highly substituted P-hydroxycyclopentanecarboxylates are generated in the process, with substantial and predictable stereochemical control at three contiguous stereocenters.