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ChemInform Abstract: Rhodium(I)-Catalyzed 1,4-Silicon Shift of Unactivated Silanes from Aryl to Alkyl: Enantioselective Synthesis of Indanol Derivatives.

✍ Scribed by Tobias Seiser; Nicolai Cramer

Publisher: John Wiley and Sons
Year: 2011
Weight: 73 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201118149

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✦ Synopsis

Abstract

A C~aryl~—Si bond activation and 1,4‐Si shift of unactivated tetraorganylsilanes is readily achieved in the presence of chiral Rh—difluorphos complex to give silylmethylindanols, e.g. (II), in good stereoselectivities (up to 99% e.e.

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