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Rhodium(I)-Catalyzed 1,4-Silicon Shift of Unactivated Silanes from Aryl to Alkyl: Enantioselective Synthesis of Indanol Derivatives

✍ Scribed by Tobias Seiser; Dr. Nicolai Cramer

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 361 KB
Volume: 122
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.201005399

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Rhodium(I)-Catalyzed 1,4-Silicon Shift o

Rhodium(I)-Catalyzed 1,4-Silicon Shift of Unactivated Silanes from Aryl to Alkyl: Enantioselective Synthesis of Indanol Derivatives

✍ Tobias Seiser; Dr. Nicolai Cramer 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 396 KB 👁 1 views

ChemInform Abstract: Rhodium(I)-Catalyze

ChemInform Abstract: Rhodium(I)-Catalyzed 1,4-Silicon Shift of Unactivated Silanes from Aryl to Alkyl: Enantioselective Synthesis of Indanol Derivatives.

✍ Tobias Seiser; Nicolai Cramer 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 73 KB 👁 1 views

## Abstract A C~aryl~—Si bond activation and 1,4‐Si shift of unactivated tetraorganylsilanes is readily achieved in the presence of chiral Rh—difluorphos complex to give silylmethylindanols, e.g. (II), in good stereoselectivities (up to 99% e.e.