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ChemInform Abstract: Enantioselective 1,4-Addition of Aliphatic Grignard Reagents to Enones Catalyzed by Readily Available Copper(I) Thiolates Derived from TADDOL.

โœ Scribed by D. SEEBACH; G. JAESCHKE; A. PICHOTA; L. AUDERGON


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantioselective Co
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Enantioselective Copper-Catalyzed 1,4-Addition of Organozinc Reagents to Enones Using Chiral Oxazoline-Phosphite Ligands. -The enantioselective 1,4-addition of organozinc reagents to ฮฑ,ฮฒ-unsaturated ketones in the presence of chiral P,N-ligands (I) with a binaphthyl phosphite group and an oxazoline