ChemInform Abstract: Rhodium-Catalyzed Cyclic Carbonylation of 2-Alkynylphenols: Synthesis of Benzofuranones and Coumarins.
β Scribed by E. YONEDA; T. SUGIOKA; K. HIRAO; S.-W. ZHANG; S. TAKAHASHI
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
Novel Rhodium-Catalyzed Cyclic Carbonylation of 2-Phenylethynylbenzoates Leading to Indeno(1,2-c)isocoumarin. -Pentaethynylbenzoates (I) having a neighboring ester group undergo simultaneous carbonylation of the acetylene, C-H bond activation of the phenyl group and C-O bond fission of the ester gro