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ChemInform Abstract: Rhodium-Catalyzed Cyclic Carbonylation of 2-Alkynylphenols: Synthesis of Benzofuranones and Coumarins.

✍ Scribed by E. YONEDA; T. SUGIOKA; K. HIRAO; S.-W. ZHANG; S. TAKAHASHI


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: Novel Rhodium-Catal
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Novel Rhodium-Catalyzed Cyclic Carbonylation of 2-Phenylethynylbenzoates Leading to Indeno(1,2-c)isocoumarin. -Pentaethynylbenzoates (I) having a neighboring ester group undergo simultaneous carbonylation of the acetylene, C-H bond activation of the phenyl group and C-O bond fission of the ester gro