ChemInform Abstract: Rhodium-Catalyzed Dehydrogenative Borylation of Cyclic Alkenes.
β Scribed by Azusa Kondoh; Timothy F. Jamison
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Rhodium-Catalyzed Intramolecular Silylformylation of Alkenes. -For the first time the silylformylation of alkenes is described. In every case the diastereomeric aldehydes are the major products. Small amounts of the diastereomeric hydrosilylation products are the only by-products. -(LEIGHTON,
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## Abstract Electronically activated alkenes, nonelectronically activated, sterically less demanding alkenes as well as cyclooctene are selectively diborylated under catalysis of palladium complexes (Ia) or (Ib).