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ChemInform Abstract: Efficient Synthesis of Diborylalkenes from Alkenes and Diboron by a New PSiP-Pincer Palladium-Catalyzed Dehydrogenative Borylation.

✍ Scribed by Jun Takaya; Naohiro Kirai; Nobuharu Iwasawa

Publisher: John Wiley and Sons
Year: 2011
Weight: 63 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201204154

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✦ Synopsis

Abstract

Electronically activated alkenes, nonelectronically activated, sterically less demanding alkenes as well as cyclooctene are selectively diborylated under catalysis of palladium complexes (Ia) or (Ib).

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