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ChemInform Abstract: Rh-Catalyzed Intermolecular and Enantioselective [4 + 2] Cycloaddition of 1,3-Dienes with Dimethyl Acetylenedicarboxylate.

โœ Scribed by Takanori Shibata; Daisuke Fujiwara; Kohei Endo


Publisher
John Wiley and Sons
Year
2008
Weight
49 KB
Volume
39
Category
Article
ISSN
0931-7597

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Directed Intermolecular (4 + 2) Cycloaddition of Unactivated 1,3-Diene Substrates with High Regio-and Stereoselectivities. -Pd(0)-catalyzed cycloaddition of vinylallenes with ordinary 1,3-dienes leads to cyclohexene derivatives. High regio-and stereoselectivities are achieved under mild conditions